Then, the stress corrosion cracking mechanism for various materials in. Modeling and experimental insights of sulfide stress cracking corrosion mechanism available for download a model was built that describes stress field and hydrogen activity at the direct vicinity of a. Corrosionpedia what is sulfide stress cracking ssc. Stress corrosion cracking, a very important topic of machine design. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Pdf sulfide stress corrosion cracking and hydrogen induced.
May 06, 2014 stress corrosion cracking, a very important topic of machine design. Wet hydrogen sulfide h2s cracking inspectioneering. Materials resistant to sulfide stress cracking in corrosive petroleum refining. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfur in feed gas in chemical and petrochemical plants led to. Effect of coldwork on sulphide stress cracking resistance twi. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Crevice corrosion filiform corrosion underfilm corrosion pitting corrosion microbiologically influenced corrosion mic biological corrosion, bacterial corrosion, microbial corrosion. Sulfide stress cracking and corrosion fatigue of steels. Hydrogen sulfide h 2 s is a naturally occurring gas that can be deadly to humans and corrosive to oil and gas equipment, especially in the presence of water. Materials in the sour environment are susceptible to sulfide stress corrosion cracking ssc and hydrogeninduced cracking, hydrogen embrittlement and exfoliation hehic that leads to various modes of failure including stepwise cracking, hence the importance during the design stage on material selection. Ansinace mr0175hd2003sg metals for sulfide stress cracking. Jul 10, 2019 methanolinduced corrosion is a type of corrosion induced by methanol.
Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. The mechanism of sulfide stress cracking involves a combination of stress corrosion cracking and hydrogen embrittlement. Sulfide stress cracking ssc testing southwest research. The blistering damage tends to form parallel to the. Hydrogen sulfide, when dissolved in water, is involved in a series of chemical reactions in the. Evaluates the influence of hydrogen on the mechanism of sulfide stress corrosion cracking of pipeline steels. Stress corrosion cracking behavior of 9010 cuni alloy in. Stress corrosion cracking behavior of coldworked and. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials.
Modeling and experimental insights of sulfide stress cracking. Chloride stress corrosion cracking in austenitic stainless steel. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Sulfide stress cracking of nickelcontaining lowalloy steels in. Bastien and amiot, mechanism of the effect of ionized. Results and analysis of four point bend sulfide stress corrosion cracking tests on girth weld specimens in api5l x65 material have shown that the application of cyclic prestrain to simulate the strains induced by commercial pipereeling operations affected the sulfide stress corrosion cracking resistance. Im hoping to add to the contributions in this field of research by taking the time to archive notable events in my lab. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. H 2 s becomes severely corrosive in the presence of water. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The corrosive environments which cause scc in any material are fairly specific, and the more common combinations are listed in table 33. Generally, when designing against stress corrosion cracking, e. This standard presents metallic material requirements to provide resistance to sulfide stress cracking ssc andor stress corrosion cracking scc for petroleum production, drilling, gathering and flow line equipment, and field processing facilities to be used in hydrogen sulfide h2sbearing hydrocarbon service.
The national association of corrosion engineers nace test method tm0177 is widely used to qualify metals for resistance to sulfide stress cracking and stress corrosion cracking in h 2 s environments. Hydrogen embrittlement is a function of the hydrogen absorption characteristics of the metal in the aggressive environment, which is the formation of molecular hydrogen from atomic hydrogen within the metal structure 160. Particular focus was placed on environmentally assisted cracking eac, namely hydrogeninduced cracking hic, stepwise cracking swc, stress corrosion cracking scc and sulfide stress cracking. In the case of chloride stress corrosion cracking of the 330 series austenitic stainless steels it is generally considered that the risk is minimal below approximately 60c.
Sulfide stress cracking of nickelcontaining lowalloy steels. H 2 s can cause sulfide stress cracking of stainless steels. The scc behavior of the alloy was studied in dilute and concentrated na 2 s solutions at room temperature. Pdf the wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of. Hydrogen sulphide stress corrosion cracking in materials for. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Nickel additions to las are advantageous for components designed to sustain high. Stress corrosion cracking has been observed in absolute methanol.
There is also a longstanding debate on the naming of corrosion, which includes a variety of more specific type with names such as sulfide stress corrosion cracking, hydrogenassisted stress corrosion cracking. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Modeling and experimental insights of sulfide stress cracking corrosion mechanism available for download a model was built that describes stress field and hydrogen activity at the direct vicinity of a crack tip. Succession of changes in the hydrogenation of steels depending on the stresses and. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Introduction in the united states currently there are approximately 104 operating light water reactors. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Relation between the occurrence of the brittle fracture of specimens and the achievement of critical hydrogen concentration. This condition can lead to embrittlement of the material, resulting in cracking under the combined action of tensile stress and corrosion. Sulfide stress cracking ssc is one of the most dangerous types of pipelines destruction. The stress corrosion cracking scc of 9010 cuni alloy in sulfide solutions is not reported in the literature.
The variation of the name is due to the lack of agreement in the mechanism of failure. The role of hydrogen in sulfide stress cracking in low alloy steels. Sulfide stress cracking ssc was first identified and the mechanism outlined in the. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Environmental cracking is a general term that includes. It is a recognized problem in the gas and oil industries, pipelines, municipal sewage treatment systems, and a variety of industrial applications. Chloride stress corrosion cracking scc is about as well known as any scc mechanism can be, so i wont dwell much on it here, but want to mention it for the sake of completeness and hopefully mention something that is not as commonly known about it. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Pdf electrochemical and sulfide stress corrosion cracking.
The obtained data indicates an interesting mechanism that governs intergranular stress corrosion cracking. Sulfide stress cracking nace mr01752002, mr0175iso 15156. The present understanding may enable rational design and. Scc is highly chemically specific in that certain alloys are likely. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel. Some researchers consider sulfidestress cracking a type of stress corrosion. Some researchers consider sulfidestress cracking a type of stresscorrosion. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Pdf the electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and. Material selection for sour service environment pipeline. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Modeling and experimental insights of sulfide stress.
This study is to identify factors responsible for loss of production due to problems in plant and equipment. Intergranular stress corrosion cracking weld decay knifeline attack kla exfoliation layer corrosion. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Sulphide stress cracking is prevented by minimising the hardness and. Role of hydrogen in the sulfide stresscorrosion cracking of.
The effect of slow plastic and elastic straining on sulphide stress cracking and. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Strain and sulfide stress cracking in pipeline girth welds twi. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Mechanistic model of stress corrosion cracking scc iopscience. The interaction of corrosion fatigue and stresscorrosion. In this respect, sulfide stress cracking and corrosion fatigue tests were conducted to study how a corrosive environment containing h2s and inservice loading affect the serviceability of different steel grades designed to be used for components such as drill collars and heavy weight drill pipes. Types of corrosion materials selection guide swagelok. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Providing resistance to sulfide stress corrosion cracking. Hydrogen concentration in the specimens after holding under different loads. Ian sutton, in plant design and operations second edition, 2017.
Thermal impact of the welding process drives to heterogeneity of the microstructure and properties of the. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. The presence of flaws that concentrate stress or crevices that alter. Cracking mechanism an overview sciencedirect topics.
Kallol mondal,department of metallurgy and material science,iit kanpur. A study on the mechanism of stress corrosion cracking of duplex stainless steels in hot alkalinesulfide solution. Sour gas cracking, also known as sulfide stress cracking ssc, is the deterioration of metal due to contact with hydrogen sulfide h 2 s and moisture. A study on the mechanism of stress corrosion cracking of. Pdf sulfide stress corrosion cracking and hydrogen. Petch 1987, meanwhile, proposed a mechanism based on alloy softening at low. Stress corrosion cracking the international institute of. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Factors affecting the sulfide stress cracking performance of. For this reason, it is crucial to understand eac mechanisms and kinetics and to. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. The effects of sulfide stress cracking on the mechanical properties.
The design of industrial structures and components is usually based on tensile. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. In an ideal world a stress corrosion cracking control strategy will start operating at the design stage, and will focus on the. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Stress corrosion cracking of low strength, low alloy nickel steels in sulfide environments. Sulfide stress cracking an overview sciencedirect topics. Petch 1987, meanwhile, proposed a mechanism based on alloy softening at. An enormous amount of failures have been attributed to stress corrosion cracking over the last century. Basically, stress corrosion cracking susceptibility is a function of hydrogen sulfide. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas.